Pengaruh Penambahan Nikel (Ni) Terhadap Sifat Stuktur Kristal Dan Morfologi MOF-5
DOI:
https://doi.org/10.552273/jms.v2i02.165Keywords:
Metal Organic Framework, MOF-5, Doping, NikelAbstract
Ni-doped MOF-5s were successfully synthesized by the solvothermal method for 12 hours at 140 °C. The mmol ratio of Ni/Zn was varied, i.e 0,05 and 0,1, to study the effect of Ni(II)-doped on the formation of MOF-5 materials. The Ni-MOF-5 materials were characterized using X-ray diffraction and scanning electron microscopy-energy dispersive X-ray (SEM-EDX). The XRD patterns and morphology of the Ni-MOF-5 were similar to that of synthesized MOF-5 and standard. The results of SEM-EDX showed that nickel was found in the Ni-MOF-5.
References
Anonim, (Rabu, 30 Maret 2022). Kemenperin Inisiasi Hidrogen Jadi Sumber Energi Sektor Industri. Diperoleh dari https://kemenperin.go.id/artikel/23201/Kemenperin-Inisiasi-Hidrogen-Jadi-Sumber-Energi-Sektor-Industri
Feng, Y., Jiang, H., Chen, M., dan Wang, Y. (2013) Construction of interprenated MOF-5 with high mesoporosity for hydrogen storage at low pressure. Powder Technology, 38-42
Hasan, M.S., dan Widayat, (2022). Produksi Hidrogen dengan Memanfaatkan Sumber Daya Energi Surya dan Angin di Indonesia. Jurnal Energi Baru dan Terbarukan: Universitas Diponogoro, 3 (1), 38-48.
Jahan, M., Bao, Q., Yang, J.X., dan Loh, K.P. (2010) Structure-directing role of graphene in the synthesis of metal-organic framewok nanowire. J. Am. Chem. Soc 132, 14487-14495.
Lee, S. Y. dan Park, S.J. (2011) Effect of platinum doping of activated carbon on hydrogen storage behaviors of metal-oganic framework-5. International Journal of Hydrogen Energy 36, 838-8387
Li, H.W., Shi, W., Zhao, K., Li, K., Bing, Y., dan Cheng, P. (2012) Enhanced hydostability in Ni-doped MOF-5. In Organic Chemistry 5, 9200-9207.
Venna, S.R., Jasinski, J.B., dan Carreon, M. A. (2010) Structural evolution of Zeolitiz Imidazolate Framework-8. Journal of American Chemical Society 132, 18030-18033.
Yang, S., Cuesta, A. J., dan Schr?der, M. (2013) Inelastic neutron scattering study of binding of para-hydrogen in an ultra-microporous metal-organic framework. Chemical Physics 428, 111-116.
